Selective formation of light olefins from dimethyl ether over MCM-68 modified with phosphate species

Selective production of light olefins from methanol over desilicated highly siliceous ZSM-5 nanocatalysts

Highly siliceous ZSM-5 nanocatalysts can dehydrate methanol to a wide range of hydrocarbons. In this study, the development of hierarchical H-ZSM-5 nanocatalysts (Si/Al=200) were reported for the methanol-toolefins (MTO) reaction. The nanocatalysts were prepared through a hydrothermal technique and treated by NaOH desilication. The parent and desilicated nanocatalysts were characterized using F...

Selective formation of propylene by hexane cracking over MCM-68 zeolite catalyst.

Dealumination of MCM-68 zeolite with MSE topology enhanced the selectivity to propylene (45-50%) and durability to coke formation during hexane cracking, regardless of the reaction temperature, which is attributed to the control of the position and density of acid sites originating from the framework Al atoms.

CFD modeling for selective formation of propylene from methanol over synthesized Mn-substituted MFI metallosilicate catalyst

The high silica Mn-substituted MFI metallosilicate catalyst with Si/Al molar ratio of 220 and Si/Mn molar ratio of 50 was successfully synthesized by hydrothermal method. The catalyst sample was appropriately characterized by XRD, FE-SEM, EDX and BET techniques. The Mn-substituted MFI metallosilicate has not been reported as the potential catalyst for the methanol to propylene (MTP) reaction. T...

Dehydration of Methanol to Dimethyl Ether Employing Modified H-ZSM-5 Catalysts

Selective Formation of Light Olefins from CO+H2 Over Silica Supported Co/CeO2 Prepared by Fusion Method: Preparation, Characterization and Operational Conditions Effects

The catalyst containing 80%Co/20%Ce/15wt%SiO2 was prepared using fusion procedure and studied for the conversion of synthesis gas to light olefins. The effect of a range of operating variables such as the pressure, temperature and H2/CO molar feed ratio on the catalytic performance of fused catalyst was investigated. It was found that the best operating conditions are H2/CO=2/1, T=350 ̊C and P=2...